Overview of Phosphorus Effect in Molybdenum-Based Hydrotreating Catalysts Supported on Ordered Mesoporous Siliceous Materials

نویسندگان

  • Rafael Huirache-Acuña
  • Eric M. Rivera-Muñoz
  • Trino A. Zepeda
  • Rufino Nava
  • Barbara Pawelec
چکیده

This chapter presents an overview of the literature on the effect of phosphorus modification of ordered mesoporous silica (OMS) such as MCM-41, HMS, SBA-15, and SBA-16 to be used as supports for hydrotreating catalysts based on transition metal sulfides (TMS). The influence of the support modification with variable quantities of phosphorus on the performance for hydrodesulfurization (HDS) and hydrodenitroge‐ nation (HDN) reactions is outlined and discussed considering the changes in the structural and textural properties (SBET), acidity, reducibility, etc., of the substrate brought about by phosphorus incorporation.

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تاریخ انتشار 2018